水解-水热体系中同质异构TiO2纳米晶生成机理的分子模拟研究

在实验研究的基础上,采用分子模拟的方法,对在水解-水热体系中TiO2纳米颗粒晶相生成原理进行了系统的模拟计算和建模研究,文章介绍了分子模拟软件Hyperchem的计算方法,建立了钛离子水解过程和能量分布模型,利用模拟计算和模型,直观和定量分析了水解中间产物、水热晶化过程以及最终产物间的关系。研究了pH值对同质异构相成因的影响机理;静电场作用对同质异构相生成的影响。考察了水合络离子的连接方式,指出顶角连接与棱边连接保持到最终产物的结构中。从能量的角度揭示了同质异构TiO2晶型成因。     

Anisotropic geodesics for live‐wire mesh segmentation

We present an interactive method for mesh segmentation that is inspired by the classical live‐wire interaction for image segmentation. The core contribution of the work is the definition and computation of wires on surfaces that are likely to lie at segment boundaries. We define wires as geodesics in a new tensor‐based anisotropic metric, which improves upon previous metrics in stability and feature‐awareness. We further introduce a simple but effective mesh embedding approach that allows geodesic paths in an anisotropic path to be computed efficiently using existing algorithms designed for Euclidean geodesics. Our tool is particularly suited for delineating segmentation boundaries that are aligned with features or curvature directions, and we demonstrate its use in creating artist‐guided segmentations.     

Phase Assemblages of Pr α-sialon Derived from SHS-ed Powders and TEM Study on the Nucleation of Pr α-sialon

The Pr α-sialon powders prepared by self-propagating high-temperature synthesis (SHS), consisting of 55 wt% Pr α-sialon and 45 wt% of β-sialon (abbreviated as α' and β'), were hot-pressed at 1800°C for 1 h. The results showed that Pr α' phase would transfer to β' with the appearance of JEM phase (Pr(Si_{6− z} Al _z )(N_{10− z} O _z )) after sintering, thus resulting in the increase of β' phase to 86 wt%. The addition of Y₂O₃ into SHS-ed Pr α' powders as the starting materials restrains the transformation of α' to β' and prevents the formation of JEM phase as well. The nucleation mechanism of Pr α' grain during hot-pressing was investigated in terms of transmission electron microscope and energy-dispersive spectrometer analysis. Two nucleation modes of Pr α' grains were found, i.e., nucleating on the undissolved Pr α' grains and on the nuclei of (Pr, Y) α' grains precipitated from liquid phase.     

Phase evolution and thermophysical properties of high-entropy RE2(Y0.2Yb0.2Nb0.2Ta0.2Ce0.2)2O7 oxides

Pursuing novel thermal barrier–coating materials with lower thermal conductivity and high-temperature stability can simultaneously improve the working efficiency and service temperature of a gas turbine. In this study, a series of high-entropy RE₂(Y_0.2Yb_0.2Nb_0.2Ta_0.2Ce_0.2)₂O₇ (RE = La, Nd, Sm, Gd, Dy, and Er) oxides were prepared though solid-state reaction. Through tuning the rare-earth cations, an order–disorder transition occurs from certain partially ordered weberite structure (C222₁) to disordered defective fluorite structure (Fm$\overline{3}$m). All the high-entropy RE₂(Y_0.2Yb_0.2Nb_0.2Ta_0.2Ce_0.2)₂O₇ oxides possess low thermal conductivity in the range of 0.91–1.34 W m⁻¹ K⁻¹ at room temperature, which can be attributed to increased lattice anharmonicity and disorder, resulting in additional phonon scattering. Herein, we proved that the incorporation of heterovalent cations at B-sites in high-entropy A₂B₂O₇ crystals is an effective strategy to reduce the thermal conductivity without compromising the decrease of oxygen vacancy. Moreover, the high-entropy RE₂(Y_0.2Yb_0.2Nb_0.2Ta_0.2Ce_0.2)₂O₇ oxides show the relatively higher thermal expansion coefficients of 10.3–10.7 × 10⁻⁶°C⁻¹ and excellent phase stability at elevated temperatures.     

剖析10 kV及以下电力线路设计

电力线路是电力系统的重要组成部分,其设计质量与电力系统的供电质量有着直接的关系。在设计电力线路时,需要综合考虑地形地貌、气候环境等各种因素。因此,加强电力线路的设计管理是十分必要的。     

凝结水再循环管道振动原因及减振措施

对比了福建省内某电厂一期、二期工程600 MW发电机组凝结水再循环管道的设计和布置,经过分析,得出了一期管道振动的原因。在二期设计中做出了一些改进,基本解决了凝结水再循环管道的振动问题。     

改性聚酰亚胺在摩托车中的应用

本研究选择了改性聚酰亚胺、改性聚甲醛、改性尼龙三种材料应用于摩托车衬套制品,进行了对比试验,结果表明:采用改性聚酰亚胺的衬套具有强度高、耐磨损、尺寸稳定性好等特点,完全达到该产品设计的要求。     

基于前向预测并行追踪的视频压缩传感方法

为了减小视频信号采集端的负担,提出一种基于压缩传感理论的视频压缩算法模型。该模型采用广义轮换矩阵获取视频帧的测量值,再结合视频压缩的运动补偿预测关键技术,消除视频帧间冗余。然后在并行贪婪追踪算法中引入前向预测技术作为重构算法,最终获取重构的压缩图像。实验对比了在不同算法下的重构图像和不同采样比下不同算法的重构PSNR值,然后利用所提方法得到视频序列的重构压缩图像。实验结果表明,该算法模型能较精确地获取压缩的视频图像,适合在视频压缩中应用。     

粉煤灰填充PVC树脂的研究

采用ＷＡＸＤ、ＳＥＭ和力学测试等方法对不同粒度和不同含量的粉煤灰（ＰＦＡ）与聚氯乙烯（ＰＶＣ）共混物的结构形态、力学性能进行了测定。结果表明，ＰＦＡ粒度对ＰＶＣ／ＰＦＡ共混物的性能具有明显影响，当ＰＦＡ粒度尺寸达到一定程度时，再降低ＰＦＡ粒度尺寸对共混物的性能影响不大。随着ＰＶＣ／ＰＦＡ共混物中ＰＦＡ含量的增加，拉伸强度和拉伸模量增大，但伸长率降低。     

抗静电可染丙纶的结构与性能

研究了聚丙烯、抗静电组分、可染组分三元共混体系纤维的抗静电性能、力学性能、染色性能及形态结构。研究表明：抗静电组分和可染组分有一定的相互影响，当抗静电组分加入量在４％～６％；而可染组分加入量在８％～１０％时为共混体系的最佳配合范围，共混纤维成品丝既表现出良好的抗静电性能，又表现出良好的可染性能，实现了常压沸染深色的效果。还发现，共混纤维拉伸丝的比电阻小于卷绕丝的比电阻。